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課程名稱 |
高等無機化學一
ADVANCED INORGANIC CHEMISTRY (I) |
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開課學期 |
99-1 |
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授課對象 |
理學院 化學所化學組 |
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授課教師 |
王 瑜 |
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課號 |
Chem7029 |
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課程識別碼 |
223EM1410 |
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班次 |
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學分 |
3 |
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全/半年 |
半年 |
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必/選修 |
必修 |
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上課時間 |
星期二2(9:10~10:00)星期四3,4(10:20~12:10) |
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上課地點 |
化121化121 |
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備註 |
本課程以英語授課。本課程以英語授課。外系所學生選修需經授課教師同意。
限碩士班以上
總人數上限：50人 |
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Ceiba 課程網頁 |
http://ceiba.ntu.edu.tw/991adv_inorgchem |
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課程簡介影片 |
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核心能力關聯 |
核心能力與課程規劃關聯圖 |
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課程大綱
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為確保您我的權利,請尊重智慧財產權及不得非法影印
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課程概述 |
Outline
I. Symmetry & Bonding
Atomic orbitals: H-like; many electron; spectra terms
Symmetry elements; Point groups; Molecular geometries
Symmetry operator; Character table; Representation; Group theory
Applications on molecular orbitals
hybridization orbital
MO of diatomic molecule
MO of Hn
MO of delocalized pi orbitals
MO of AHn
MO of AXn
Applications on Molecular vibrations
Walsh diagram
Orbital E vs Geometry change
II. Transition Metal Chemistry
Electronic Configuration, Spectroscopy, Magnetism
Coordination Chemistry, Tanabe and Sugano Diagrams
Bonding, Structures, Reactivity & Reaction Mechanisms
III. Main Group Chemistry
Ionic & Covalent Bond, Chemical Forces, H-Bonding & Acid-Base Chemistry
Structures & Reactivity
Supramolecular Chemistry & Organometallic Chemistry
A Brief Introduction on Modern Development
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課程目標 |
Bonding, Structure, Reactivity, Mechanism, and Applications of Inorganic Compounds |
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課程要求 |
先修科目 Pre-requistes 1. General Chemistry 2. Inorganic Chemistry, Undergraduate Level
本課程以英語授課。外系所學生選修需經授課教師同意。與劉陵崗教授合開。
限碩士班以上。總人數上限：50人
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預期每週課後學習時數 |
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Office Hours |
另約時間 |
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指定閱讀 |
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參考書目 |
1. F. Albert Cotton; "Chemical Applications of Group Theory"; Wiley-
Interscience; 1990; 3rd Edition.
2. James E. Huheey, Ellen A. Keiter, Richard L. Keiter; "Inorganic Chemistry:
Principles of Structure and Reactivity"; Benjamin Cummings; 1997; 4th Edition.
3. F. Albert Cotton, Geoffrey Wilkinson, Carlos A. Murillo, Manfred Bochmann,
Russel Grimes; "Advanced Inorganic Chemistry"; Wiley- Interscience; 1999; 6th
Edition.
4. Gary L. Miessler, Donald A. Tarr; "Inorganic Chemistry"; Pearson Prentice
Hall; 2004; 3rd Edition.
5.Yves Jean; Francois Volatron; Jeremy Burdett;“An Introduction to Molecular Orbitals”Oxford. |
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評量方式
(僅供參考) |
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No. |
項目 |
百分比 |
說明 |
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1. |
3 Examinations |
75% |
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2. |
Assignments, Homework, Term Paper and/or Presentation |
25% |
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週次 |
日期 |
單元主題 |
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第1週 |
9/14,16 |
Atomic orbital:H-like,Many electron,Spectra terms symmetry elements,point groups,molecular geometries symmetry operator,charater table,representation,group theory |
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第1週 |
9/16 |
Applications on molecular orbital:Hybridization orbital,MO of diatomic molecule, MO OF Hn,MO of delocalized pi orbital,MO of AHn |
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第2週 |
9/21,23 |
Applications on molecular orbital:Hybridization orbital,MO of diatomic molecule,Mo of Hn,MO of delocalized pi orbital,MO of AHn |
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第3週 |
9/28 |
Applications on molecular orbital:Hybridization orbital,MO of diatomic molecule,MO of Hn,MO of delocalized pi orbital,MO of AHn |
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第4週 |
10/5,7 |
Applications on Molecular orbital:Hybridization orbital,MO of diatomic molecule,MO of Hn,MO of delocalized pi orbital,MO of AHn |
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第5週 |
10/14 |
Walsh diagram:Orbital E vs.Geometry change |
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第5週 |
10/12,14 |
Applications on Molecular vibrations
(Walsh diagram:Orbital E vs.Geometry change) |
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第6週 |
10/19 |
Walsh diagram:Orbital E vs.Geometry change(MO of AXn,MO of M(3d)Ln ) |
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第6週 |
10/21 |
MO of AXn,MO of M(3d)Ln; First exam (find the other time) |
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